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1-7: The Discovery of the Electron |
[Vacuum Discharge,
the Cathode Rays]
Put a pair of plates
(electrodes)
in a glass tube
and apply a several kV
high voltage potential
between them.
When the gas pressure
in the tube
becomes very low
(lower than 0.1
atmospheric pressure),
an electric discharge
will take place.
This is called
vacuum discharge.
We can see a striped
pattern in the tube.
An example is shown in
the picture below.
When the gas pressure
in the tube
becomes about
0.000001 atmospheric pressure,
the striped pattern
will disappear
and the inside
of the tube will
become dark.
However this does
not mean
the discharge stopped;
a current is still
passing between the electrodes.
Namely, something is flowing
between the electrodes.
These are called
the cathode rays.
The equipment
to generate the cathode rays
was named
Crookes tube
after its inventor
W. Crookes
(UK, 1832 - 1919).
In order to investigate
the properties of
cathode rays
we place a cross
in the Crookes tube
as seen in the
following figures
and set a screen
of a fluorescent substance
beyond the cross
also inside the tube.
Then we can watch
a shadow of the cross
on the screen.
This implies
that the cathode rays
emitted from the cathode
toward the anode
travel in straight lines
to the screen.
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[What are the
Cathode Rays?]
J. J. Thomson
(UK, 1856 - 1940)
investigated the true nature
of cathode rays
(1897).
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There have been
three famous British physicists
named "Thomson"
in the history
of science.
Do not confuse them.
(1)
W. Thomson
(William Thomson,
1824 - 1907).
"Lord Kelvin".
The unit of absolute
temperature K
is given after his name.
(2)
J. J. Thomson
(Joseph John Thomson,
1856 - 1940).
Under consideration
on the present page.
J. J. Thomson had
many achievements
including not only
the discovery of the electron
but the proposal
of the atomic model
discussed later
and
many other discoveries.
(3)
G. P. Thomson
(George Paget Thomson:
1892 - 1975)
A son of the above
J. J. Thomson.
G. P. Thomson
confirmed the diffraction
of electrons
with the use
of a metsllic crystal
to prove the wave
nature of electrons
independently of
the works of US physicists,
C. J. Davisson
and L. H. Germer.
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The apparatus used
by J. J. Thomson
to investigate
the properties of
cathode rays
is schematically shown
in the following
figure.
Its basic idea
is essentailly the same as that
of the Crookes tube.
J. J. Thomson presumed
that the cathode rays
that came out of
the negative electrode
(cathode)
were a collection
(beam) of
the same particles
with negative charges.
If they are so,
these particles
emitted from the cathode
would be pulled
by the positive
electrode (anode),
pass through a small hole
at the center
of the anode,
travel in a straight line,
pass between
the plates, P1
and P2,
and finally arrive
at a screen
of fluorescent substance
to make a small spot
on it.
If the electric
potential is
so applied
that the upper plate
is negative
and the lower
is positive, then
the beam would
be curved downward
and the spot on the screen
would move downward.
J. J. Thomson
observed this phenomenon,
and he also found
that the spot neither
spreaded greatly
nor faded.
We can conclude
from these results
that J. J. Thomson's
presumption is correct;
namely, the cathode rays
are a beam
of the same kind of
"particles"
with a negative charge.
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[Charge-to-Mass Ratio
of the Cathode Rays]
Using the experimental
set up discussed above,
we can measure
the charge-to-mass ratio
e /m
of the "particle"
in the cathode rays.
Here e is
the charge
of the particle and
m is its mass.
To explain the
details
of the method
to evaluate the
charge-to-mass ratio,
we need some
mathematical expressions,
which we
will explain
on another page:
1-7-A:
Measurement of the Charge-to-Mass Ratio of Cathode Rays
Using the method
explained in the other page
(1-7-A),
J. J. Thomson measured
the charge-to-mass ratio
of the particle
in the cathode rays
and got a value of
A more precise
estimate is
J. J. Thomson confirmed
that an almost
constant value
of e /m
was always obtained
under various experimental
conditions.
He therefore concluded
that cathode
rays are a collection
of the same kind
of particles.
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[The True Nature of
the Cathode Rays,
the Electron]
Let us compare
the charge-to-mass ratio
of the particle
in the cathode rays
with that of
the hydrogen ion.
As seen in
Faraday's Law of Electrolysis
on Page 1-6,
a charge of
is necessary to separate
1 gram equivalent element
through the electrolysis.
Consider the case
of hydrogen for example.
Because the valence
of hydrogen is 1
and the atomic weight
of hydrogen is about 1,
1 gram of hydrogen ions
have a charge of
.
Namely the charge-to-mass ratio
of the hydrogen ion
is about
.
Accordingly,
This inplies either
that the mass of the
"particles" in cathode rays
is about 1/1800
of the mass
of a hydrogen ion,
or that the "particle"
can carry 1800 times
more charge than
a hydrogen ion.
J. J. Thomson thought
that the latter is
not plausible.
Therfore he assumed
the former
and named the particle
in the cathode rays:
electron (1897),
whose mass is
by a factor of
about 1/1800 than
the lightest atom,
hydrogen.
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[The Mass of the Electron]
A little later than
J. J. Thomson's research
on the electron,
the value of
the elementary charge
e
was clarified
by the Millikan oil
drop experiment
as explained on Page 1-6;
Millikan's Experiment
Thus it is quite natural
that the charge of the electron
would be equal
to the elementary charge e.
Accordingly, the mass
of the electron
is determined.
Today, the data
on the electron are precisely
measured as
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[Electron as a Common
Constituent of Atoms]
Various experiments
showed that
the properties
of cathode rays
do not depend
on the kind of gas
in the discharge tube.
Moreover, when a metal
is heated to
a very high temperature
around
a large number of electrons are
emitted from it.
They are called
thermal electrons.
O. W. Richardson
(UK, 1879 - 1959)
investigated the details
of the thermal electrons.
He considered
that the electrons
in atoms in a highly
heated metal
were strongly shaken
and rushed out of the metal.
Thus he confirmed
that the electron
is one of the common
constituents of atoms.
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