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2-5: Rutherford's Atomic Model |
As discussed
in the preceding page,
we should consider that
Thomson's raisin bread model
(plum pudding model)
was unsuccessful,
because it could
not explain the results
of the alpha particle
scattering experiment
of
Geiger and Marsden.
Let us look back
upon the experimental results;
we can summarize them
as follows:
[The Results of
Geiger and Marsden's
experiment]
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(1) |
Almost all the incident
alpha particles
go straight and
are scarcely scattered.
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(2) |
Only occasionally
such a large-angle
scattering through
an angle greater
than 90 degrees
or near 180 degrees
occurs.
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(3) |
The scattering rate
(or probability)
depends on the atomic
weight of the target;
the more the atomic weight,
the larger the probability.
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[The Rutherford Model of the Nuclear Atom]
Considering the results
of Geiger and Marsden's
experiment
and the failure
of Thomson's atomic model,
E. Rutherford
(UK, 1871 - 1937)
proposed a model
in which
the electric charge +Ze
in an atom
is not distributed
over the whole area
of the atom
but concentrates
in a small area
(1911).
He thought as follows:
The charge +Ze
is localized to be
a cluster or a group
and the alpha particle
is scattered by
Coulomb's repulsive force,
(C. A. de Coulomb:
France, 1736 - 1806).
Namely, his idea is that
the large-angle scattering
of the alpha particle
is brought about
by a single scattering
due to Coulomb's repulsive force
between the charge
of the alpha particle,
+2e, and
that of the cluster,
+Ze.
The cluster is called
atomic nucleus
or simply nucleus.
Rutherford's atomic model
is often called
Rutherford model
or sometimes
Rutherford model
of the nuclear atom.
A schematic image
of the Rutherford model
is shown in the following
figure,
where a black big ball
at the center
is the nucleus and
small red points moving
around the nucleus
are electrons.
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The Rutherford Model of the Nuclear Atom
A black big ball
at the center
is the nucleus and
small red points moving
around the nucleus
are electrons.
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In 1903,
H. Nagaoka
(Japan, 1865 - 1950)
proposed a ``saturnian model'',
which was referred to
in Rutherford's paper.
You should note
that the Nagaoka's model
had been proposed
several years
before Rutherford's model.
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[Rutherford Scattering]
Rutherford investigated
whether the results
of the experiment
of the alpha particle scattering
could be explained well
by the Rutherford model
of the nuclear atom.
He derived the famous
Rutherford scattering formula
standing on the viewpoint
of the Rutherford model
and he found
that the results
of this formula
fit well to
the experimental data
(1911).
Thus the firm position
of the Rutherford model
was established.
Rutherford assumed
that the total positive
charge in an atom, +Ze,
concentrates on the central
point of the atom,
i.e., the nucleus,
and the incident alpha particle
is scattered
with a repulsive Coulomb
force exerted
by this nuclear point charge.
(See the following
figure.)
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This type of scattering
by the Coulomb force
is usually called
Coulomb scattering or
Rutherford scattering.
(See the above
figure.)
The detailed formulation
on Rutherford scattering
will be given
in the following other page.
If you feel it difficult
to understand,
skip it,
and accept the final
Rutherford scattering formula.
2-5-A:
Rutherford Scattering
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As shown in
the above figure,
the distance between
the incident line
and the nucleus
is the impact parameter
b.
If b = 0,
it is head-on collision,
where the incident alpha particle
would recoil
in the direction
of 180 degrees.
If b
is small,
the trajectory
would be curved largely.
If b is large
and the particle
goes along a path
far from the nucleus,
then the repulsive force
exerted by the nucleus
is weak and
the trajectory would not
curve so much.
Namely,
the trajectory is determined
by the impact parameter only
for a constant incident speed
v0,
This feature are shown
in the following graph
which is drawn
by using the numerical data
obtained from the solution
discussed on the page
(2-5-A).
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[Angular Distribution
of Rutherford Scattering]
As seen in the above figure,
if the incident line
is close to the nucleus
of the target atom
or if the impact parameter
is small,
the trajectory
of the alpha particle
would be largely
curved and
it would be scattered
backward.
In contrast,
if the impact parameter
is large,
then the alpha particle
goes through far
from the nucleus and
the trajectory
does not curve so much.
In the realistic experiment,
the number of the incident
alpha particles
in a unit area
is almost constant
independently of the
impact parameter.
The number of the
incident particles
in a unit area
and a unit time,
N,
is called the
intensity
of the incident alpha rays.
We may consider that
the intensity N
of the incident alpha rays
is constant.
It is called
the angular distribution
what rate among
the many incident particles
is scattered in the direction
of a certain angle.
Strictly speaking,
the angular distribution
or
differential scattering
cross section
![]()
is defined by dividing
the number of
the particles scattered
in a unit solid angle
of a certain scattering angle
![]()
in a unit time
by the intensity N.
Rutherford obtained
the differential scattering
cross section
![]()
on the basis of
Newtonian mechanics
(1911).
The details of deriving
the cross section
are explained on the page
2-5-A
The result is shown
in the following formula,
This Rutherford's formula
was well fit to experiment.
Thus the validity
of Rutherford's model
of the nuclear atom
has been established.
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As stated above,
Rutherford derived
the angular distribution
of the alpha particle scattering
on the basis
of Newtonian mechanics.
Newtonian mechanics
is sometimes called
classical mechanics,
and it was later
clarified that
Newtonian mechanics
is not always correct
in the microscopic world,
i.e.
the world of
atoms and atomic nuclei.
It has been made clear
some years later that
the correct theory
to describe such
a microscopic world
is quantum mechanics.
It has however been
clarified that,
as long as Rutherford scattering
is concerned,
both classical mechanics
and quantum mechanics
give the same angular distribution.
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[The Size of the Charge
of Atomic Nucleus]
The angular distribution
![]()
derived by
Rutherford was
very successful not only
in the angular dependence
but in a by-product.
As seen in the above
Rutherford formula,
![]()
contains a factor Z.
By measuring
this scattering
probability precisely,
we can obtain
the value of Z.
The quantity Z
is the number of the electrons
surrounding the nucleus in an atom.
Before Rutherford's formula,
the value of Z
had only been known
to be about a half
of the atomic weight.
However, precise measurements
of the angular distribution
of Rutherford scattering
have shown the precise value
of the charge
of the atomic nucleus
and also the number
of electrons in an atom.
Consequently,
it was made clear
that Z
is exactly equal
to the atomic number.
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