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1-6: Tunnel Effect |
We studied
on the preceding page
that "the probability density
that a particle will be found
is equal to the square
of the absolute value
of the wave function".
An experimental evidence
of the validity
of the above interpretation
was given
by Gamow's explanation
on the
alpha decay
of atomic nuclei.
The alpha decay of atomic nuclei
could be explained
by a strange phenomenon
called
tunnel effect.
This was an effect
inconceivable in the classical theory.
Let us learn it below.
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["State" in Quantum Mechanics]
Before getting onto
the main point
of the tunnel effect,
let us explain the concept
of "state" in quantum mechanics.
It is a basic concept
by which all the informations
on the dynamical system
under consideration,
e.g. the energy and momentum
distributions of the system,
the probability density of
the particles
in the system,
and so on,
can be obtained.
All of these informations
about the system
under consideration
must be contained
in the wave function.
So that the wave function
is sometimes called
the state function.
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[Stationary State]
Let us consider
a one-dimensional space
for simplicity.
The wave function of a free particle
is shown by
Eq. (6) on the page
"1-3: The Schroedinger Equation" as
This is a state
with a constant energy E .
Thereby we can consider that
a wave function
whose time factor is
is a state of
a constant energy E .
Let us assume
the wave function to be
As discussed above,
this state is
of a constant energy E .
Putting this into
the Schroedinger equation
we have a differential equation
independent of time t
as
which determines the
spatial part
of the wave function.
The above equation (4)
is named the
"time-independent Schroedinger
equation" or sometimes
called the
"Schroedinger equation"
simply.
In the state represented
by the wave function
of the form of
Eq. (2),
the probability density
of the particle
is written
Because this probability
is independent of time t ,
this state is called
a stationary state,
which is just
what we have met in
Bohr's old quantum theory.
The ground state
and the excited states
of hydrogen atom
are of this type of states.
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[Range of Motion of a Particle
-- Classical Mechanics]
Let us see
the vibration
of a spring
or a harmonic oscillator
as shown in Fig. (A) below.
Suppose that a mass m
is attached to the
spring and neglect
the mass of the spring
itself.
Suppose that an x axis
is arranged in the direction of
the motion of the oscillator.
Let the position
of the natural length
of the spring be x = 0.
When an energy E
is given to the mass m ,
it oscillates
within the range
between the lower bound A
and the upper bound B.
The energies of this oscillator
are graphed in the following
Fig. (B).
When the spring is extended
by x
from the equilibrium position
(natural length),
then the force exerted
on the mass is
- kx ,
where k
is the spring constant.
At this point,
the potential energy
of the oscillator is
The total energy of the spring,
E ,
is the sum of the kinetic energy
and the potential energy,
i.e.,
For a given energy E ,
the possible range
of the oscillation
is as follows:
This is the range
between A and B
on the x axis in
Fig. (B).
In Fig. (B),
the
yellow-colored part
denotes
the potential wall.
The particle motion
is confined to the inner part
of the potential
(the outside of the wall).
The particle with energy
E is reflected
by the potential wall,
and repeats a back-and-forth
motion between A and B
on the x
axis.
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[Energy Eigenvalues, Eigenstates]
Let us treat the same
oscillator motion
as discussed above
in quantum mechanics.
The quantum mechanical
state of motion
is determined
by the solutions of
the Schroedinger equation
(4).
In the present case,
it becomes
the following differential equation
The square of the absolute value
of the wave function,
,
denotes the probability density
where the particle will be detected.
So that
must be finite
over all the region of
x.
In order that
the wave function
satisfies this condition,
the corresponding energy
E
should be restricted
to some specialized values.
While the energy
E
can take
a continuous value
in the classical mechanics,
it cannot be so
in quantum mechanics.
The allowed energy
in quantum mechanics
is not continuous
but discrete
(step-like).
Such discrete energies
are called
the eigenvalues
and the corresponding states
are called
the eigenstates.
We should pay attention
to the reason
why such eigenstates
with discrete energy
eigenvalues occur.
The reason is
that the particle motion
accompanies the wave function,
i.e.,
just due to
the particle-wave duality.
The requirement
of finiteness and continuity
of the wave function brings about
the discrete energy eigenvalues.
This property
is never obtained
in the classical mechanics
and
it is a surprising result.
Namely, the stationary states
in Bohr's old quantum theory
can be derived just from
the double nature
of electrons.
The energy eigenvalues
of a harmonic oscillator
is given by
The allowed n
is 0 or positive integers.
These results are shown
in the form of energy levels
in the following
Fig. (C).
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The eigenstates
of a harmonic oscillator
The eigenvalues obtained
by solving
the Schroedinger equation
(9)
which are denoted
by the horizontal lines
(levels).
The thick solid curves
show the corresponding
wave functions.
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In this figure,
the ground state,
n = 0,
is denoted by the symbol (0),
and the excited states,
n = 1, 2, 3, ...
by
(1), (2), (3), ... , respectively.
In the case of
a harmonic oscillator,
the energy levels
(horizontal lines in Fig. (C))
are at equal intervals.
This is a distinctive feature of
a harmonic oscillator.
The thick solid curves
in Fig. (C)
show the
wave function
corresponding to each
energy eigenvalue.
These results have been
obtained by solving
the Schroedinger equation
(9).
It can be solved
analytically
but it is somewhat tedious
to explain how to solve it,
so that we omit here.
If you want to study the details,
refer to some other
textbooks on quantum mechanics.
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[Range of Motion of a Particle
-- Quantum Mechanics]
In the classical mechanics,
the particle motion
is confined to the inner part
of the potential
(the outside of
the potential wall)
as shown in Fig. (B).
The particle cannot penetrate
into the potential wall
in the classical mechanics;
i.e.,
the range of the particle
motion in the classical mechanics
is just from A to B
in Fig. (B).
However, the situation
in quantum mechanics
is different.
In Fig. (C),
the wave function
corresponding to each eigenstate
goes beyond the limits
in the classical mechanics
and it penetrates
into the potential wall.
This means that
there is a probability
that the particle will
be found inside
the potential wall.
This is a surprising fact
that we cannot imagine
in the classical mechanics.
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[Penetration Coefficient]
In order to estimate
the rate of the probability
that penetrates the
potential barrier,
let us assume a simple
square potential
as shown in the above
Fig. (E).
Here, let the width
of the square potential be
a
and the height V0.
The wave function
in the region
on the left-hand side of
the barrier
is a superposition
of the incident wave
(11)
and the reflected wave
(12);
i.e.,
Contrarily, the wave function
on the right-hand side
of the barrier
consists only of the
the penetrated wave as
Solving the Schroedinger equation,
we can determine the constants
A , B
and C .
Let us explain that
on the following other page,
1-6-A:
Calculation of the tunnel effect in a simple case.
This page is not so difficult
but, if you feel it tedious,
you may pass it.
Then you should
accept the results.
As seen in the calculation
presented on the page
1-6-A,
a relation
holds.
The quantity
denotes
the intensity of the incident wave.
And
and
denote
the intensities of
the reflected
and transmitted waves, respectively.
The above relation (15)
means therefore that
the sum of the probabilities
of the reflected particles
and the transmitted particles
is equal to 100 %.
This is nothing but
the conservation of
the probability.
The rate of the particles
penetrating the potential barrier
out of the incident particles,
i.e.
the penetration coefficient
(or transmission coefficient)
is given by
where
The function sinh
defined by
is called the
hyperbolic sine function.
An example of the
experimental evidences of
the tunnel effect
discussed in the present section
is the alpha decay
of atomic nuclei
which will be explained
on the next page.
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