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3-1: The Origin of the Nuclear Energy |
[Exothermic
Chemical Reactions]
Heat is evolved
in the chemical reaction
in which hydrogen and oxygen
are combined to be water;
i.e. the combustion
of hydrogen.
Such chemical reaction
in which heat is evolved
is called exothermic
reaction.
The chemical equation
of this reaction
for one mol of hydrogen
is written
Namely, when one mol of hydrogen
burns, 286 kJ of heat is evolved.
Another example is
where one mol of carbon
is oxidated to be
carbon dioxide
with producing
394 kJ of heat.
The above chemical equations,
(1) and (2), are for
one mol of hydrogen and carbon,
respectively.
In order to compare these chemical
reactions with nuclear reactions,
it is convenient to rewrite these
equations "for one molecule".
For this, let us divide
the heat production
by the Avogadro constant
Then they are rewritten as
Equation (3) means that
the process in which
two hydrogen and one oxygen
molecules combine to be
one water molecule
generates 3.0 eV energy emission.
And Eq. (4) says that,
when a carbon atom combines with
an oxygen molecule to be
a carbon dioxiside molecule,
4.1 eV energy is released.
As learned before,
eV is a unit of energy
extensively used
in the atomic and nuclear world.
It is the work done on an electron
that is accelerated through
a potential difference
of one volt.
Its value is
Moreover, the units of energy,
keV and MeV,
are often used in the nuclear world;
the former is 1,000 times eV
and the latter 1,000,000 times eV.
We can understand that
"the energy evolved from
one process of
an exothermic chemical reaction
is about 3 or 4 eV".
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[Exothermic
Nuclear Reactions]
Nuclei show
various types of reaction:
For example, one nuclide
splits
into two or more fragments.
This type of reaction is called
nuclear fission.
Contrarily, two nuclides sometimes
combine with each other
to be a new nuclide.
This type of reaction is called
nuclear fusion.
There are many other types of
reaction processes;
they are generally called
nuclear reaction.
Among these various types
of nuclear reactions,
there are some types of
exothermic reactions
which are sometimes called
"exoergic" reaction
in nuclear physics.
The nucleus of deuterium
atom is called deuteron
which consists of
a proton and a neutron.
It is represented by
a symbol "d".
The nuclear reaction
in which two deuterons
bind with each other is
an example of nuclear fusion.
This exoergic reaction is written as
If a neutron is
absorbed in
the uranium-235 nucleus
(
),
it would split
into two fragments
of almost equal masses
and evolves some number
of neutrons and
energy Q.
One of the equations
for the processes is written
This is an example of
nuclear fission.
Here it is quite interesting
how much the amount of the
energy emission Q
is.
It must be about 200 MeV.
Let us explain below why it is so.
The details of the mechanism
of nuclear fission and fusion
will be given
on the following pages.
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[The Origin
of the Nuclear Energy]
Let us take up
the d-d fusion reaction
shown by the above Eq. (5)
as an example.
Since the experimental value of
the binding energy
of deuteron is 2.2246 MeV,
the sum of the binding energies
of the two deuterons
before the reaction
(on the left-hand side of Eq.(5))
is 4.449 MeV.
On the other hand,
the experimental value of
the binding energy of
is 7.719 MeV.
Therefore the total
binding energy after the reaction
(on the right-hand side of Eq. (5)) is
3.27 MeV (= 7.719 - 4.449)
larger than the binding energy
before the reaction
(on the left-hand side of Eq. (5)).
Thereby the total mass
decreases after the reaction
and the mass defect corresponding
to the above increase of
the binding energy
occurs.
This mass defect is
released as the heat (or energy)
production in
this exothermic (or exoergic)
process.
Next, we shall discuss
the change of the binding energy
before and after the fission
of uranium-235
(
)
shown by Eq. (6).
As seen in the figure on
Page 2-4, [Comparison between Mass formula and Experiment] ,
the binding energy per nucleon
in nuclei around
A = 240
is about 7.5 MeV.
On the other hand,
that
in nuclei around
A = 120
is about 8.5 MeV.
Accordingly, if a uranium nucleus
splits into two fragments
with almost equal masses,
the binding energy per nucleon
would increase
by about 1 MeV
and the total mass of
the fission fragments
would decrease
by the corresponding amount.
This loss of mass
(or mass defect)
is converted into
the heat (or energy) product
Q.
Since an energy of about 1 MeV
per nucleon is released,
the total energy
Q
would be more than
200 MeV.
According to the above discussions,
it becomes clear that
"the origin of nuclear energy
is the change of nuclear masses",
and it is based on
the principle of
Einstein's Mass-Energy Equivalence.
If the total binding energy
after the reaction is larger than
before, the total sum of the masses
of the reaction products
becomes smaller than that before
the reaction.
This decrease in mass
is converted into an energy,
so that the process would be
an exothermic (exoergic) reaction.
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[The Origin of the Heat
in Exothermic Chemical Reaction,
Law of Energy Conservation]
We have learned that,
if hydrogen and carbon burn
in oxygen gas, heat or energy
is evolved.
What is the origin of this
heat or energy?
The principle of the
heat production in chemical
reaction is
just the same as
that in the nuclear reaction.
The hydrogen molecule
is a bound system of two hydrogen atoms.
The mass of a hydrogen molecule
is slightly smaller than
the sum of the masses of two hydrogen atoms.
Converting this
difference (= mass defect)
into an energy with
Einstein's Mass-Energy Equivalence,
we have the binding energy
of the hydrogen molecule.
In the process of
combustion of hydrogen
represented by Eq. (3),
the total mass
after the reaction
is slightly smaller
than before,
and this decrease in mass
is transformed into the heat emission
in the exothermic reaction.
Strictly speaking,
conservation
of mass does not hold
even in a chemical reaction.
Both in chemical and
nuclear reactions,
the energy of the total system
with converting mass into energy
conserves before and after
the reaction.
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[Huge Amount of Nuclear Energy]
Comparing Eq. (3) with (5),
and Eq. (4) with (6),
we can easily understand
that the nuclear reactions
yield a huge amount of energy
in comparison with
ordinary combustion processes.
As explained above,
"the energy evolved from
an exothermic chemical reaction
like combustion of hydrogen or carbon
is about 3 or 4 eV".
In contrast,
d-d fusion reaction
shown by Eq. (5) releases
3.27 MeV of energy.
It is about several million times
as large as the ordinary combustion.
In the fission of
uranium-235 shown by Eq. (6),
the more energy than 200 MeV
is emitted.
It is about several 100 million times
as large as an ordinary
chemical reaction.
Thus, the nuclear energy
released in nuclear fission and fusion
is several million
or
100 million
times as large as
an ordinary chemical
reaction like a combustion
process.
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